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Articles / chemistry

chemistry

How to Make Better Functional Chocolate with Food Science

November 9, 2022 by Alan McClure

Have you noticed that nearly all the functional chocolates available these days range from waxy and cloying, to mediocre and just barely tolerable?

Trust me, I’m a scientist—I’ve carried out careful sensory evaluation on a significant sample size of the functional chocolates. The results have been…disappointing. But I’m still hopeful. Why?

Because it means there’s a huge opportunity for a functional foods company (like yours) to corner the market niche of high-quality functional chocolate.

Until that happens though, we’re all consigned to gulping down “chocolates” that taste like muddy, bittersweet medicine. Gross.

At least each dose is small enough to take down in a bite or two…

But what if I told you that functional chocolate can be as fantastically flavored and gourmet as anything you’d find in a San Francisco Whole Foods or from a multi-generation French chocolate maker?

It just takes a little focused food science and finesse.

How to use functional ingredients in chocolates

I’m glad you asked. Whether you are trying to incorporate CBD, melatonin, or a newly available functional ingredient into your chocolate—high quality functional ingredients should be your starting point for making functional chocolate, not an afterthought.

Most functional chocolate producers add their functional ingredients almost as an afterthought. It’s just there to pack a punch and deliver a dose. So they can boast some fantastic milligram total on the packaging, and shove mediocre products down our greedy throats.

But don’t our greedy tongues deserve to be in on the experience too? Shouldn’t the chocolates we eat TASTE as good as they are a benefit to our health?

If you agree, here’s the start of an answer:

Think of your functional ingredient as a flavor ingredient. Not just a magic or medicinal one.

If it has clear aroma, bitter, or astringent notes, for example, these should be considered as components of the product from the ground up, not at the final moment.

What’s the best functional ingredient for chocolate?

First and foremost, invest in high-quality ingredients that have minimal off-flavors, if possible. In poorly purified ingredients there can be an array of unpleasant flavors. This is particularly common in the growing edibles industry.

But this is usually avoidable, because there are often a number of functional ingredient producers/vendors representing a range of qualities from cheap and dirty tasting, to clean and virtually without aroma, even if bitterness still needs to be dealt with. 

Because don’t your customers deserve better?

So why would you use anything other than high-quality ingredients in functional chocolates?

How to make high-quality functional chocolate?

Be thoughtful about every ingredient!

Making top quality chocolate always revolves around at least three main taste elements: sweet, bitter, and sour. Not to mention aroma and other sensory characteristics like astringency.

Cocoa is naturally bitter, and so are many functional ingredients. To compensate for the bitterness of functional ingredients, many brands will simply drop the cocoa percentage and drive up the sugar. But all of that sweetness also drives out the complexity.

There are many ways to mask, balance, and/or incorporate bitterness in functional foods, such as CBD-containing edibles, but remember—every adjustment you make in a chocolate recipe has a ripple effect.

Choosing ingredients that enhance existing flavors while naturally balancing those that tend to be more unpleasant, can go a long way toward creating top-quality functional chocolate to enchant the market. There are many ingredients we can use with this seemingly magical ability. If you’re wondering, one such great example is sea salt. It packs a huge punch when it comes to enhancing flavor of virtually any product.

Also, remember…

You don’t need to go bean-to-bar for gourmet functional chocolate

As a functional chocolate producer, you’re better off as a chocolatier rather than a chocolate maker. Going all the way back to the bean adds little to your goals and process except extra steps and stress.

Chocolate maker is someone who makes chocolate from scratch, using different percentages of cacao (cocoa beans that need to be sourced, roasted, and further processed) and other ingredients.

Chocolatier sources finished chocolate from a chocolate maker, and adds ingredients and flavors to create their own bar or confection.

You should certainly source one or more high-quality chocolates that will pair well with the flavor and aroma profile of whichever functional ingredient(s) you choose. And another thing…

Don’t try to cram maximum functional ingredients into every bite

Not only does that let your customer enjoy a few more bites of your delicious chocolate per dose, but decreasing the density of functional ingredient also automatically decreases the bitterness you have to deal with.

This can work on a marketing level too. Who sells more bars? The brand with 10 doses per bar, or the one that is super delicious and mouthwatering, costs less, and sacrifices only a few doses?

Summary: How does food science lead to better functional chocolate?

When it comes to formulating the best functional chocolate for the market, there are a lot of elements to consider.

  • Functional ingredients vendors
  • Format of the functional ingredients (oils, powders, etc.)
  • Dosage
  • Cocoa percentage
  • Mouthfeel
  • Appearance
  • Sweet, sour, bitter balance
  • Overall flavor bouquet

As a food scientist with a PhD in flavor chemistry, when it comes to functional chocolate formulation, one of my most important and unique tools is formal experimental-design. I have the software, lab experience, and deep knowledge of taste and flavor on a molecular level that you can’t get anywhere else.

And by the way, before becoming a functional food science consultant, I was for many years an award-winning chocolate maker and confectioner, with additional experience in formulation of bakery items, ice cream, beverages, and more.

Any worthwhile chocolate consultant could hopefully help you source a decent chocolate; but only food science can help you pinpoint the best possible version, based on multi-variable experiment setup, multi-objective optimization, and formal sensory analysis (including consumer testing, if you have the budget and time).  

So what it comes down to fundamentally is this: What are you trying to achieve?

Are you trying to make excellent-quality functional chocolate that loyal customers will buy over and over again because it’s so delicious?

Or are you just trying to get a bunch of one-time sales?

If you answered Yes to the first question, reach out and let’s formulate some gourmet functional chocolate at a quality level that still rarely exists in the functional foods market.

MORE: Want to see more about how functional chocolate formulation works? Follow us on LinkedIn!

Filed Under: All posts, CRAFT, SCIENCE Tagged With: chemistry, experimental design, flavor chemistry, food science, product development, science

Product Formulation Optimization #2

September 28, 2021 by Alan McClure

The Troublesome Yet Terrific Tortilla (Part 2)

Continuing on with the product formulation optimization theme, using tortilla formulation specifically as an example, we dig in further. As a reminder, tortilla formulation is more complicated than it may at first appear. As I wrote previously:

“From the standpoint of the uninitiated, a tortilla seems a simple beast. As a plain product on its own there are no fillings or inclusions, no added flavors, swirls of color, or fancy shapes. Even the plastic bags in which they’re sold ten at a time are nothing special. But the phrase “deceptively simple” does exist for a reason. And one could reasonably argue that it was coined as a product formulation expert was doing some deep thinking about the common, yet commonly unimpressive, tortilla.”

In this recent post I also spoke about the two different types of tortillas (corn and wheat flour), and noted some of the complexities of both of them including nixtamalization in the case of corn tortillas, and the presence of gluten and necessary added fat in the case of the wheat flour tortillas. Clearly, when done well, both types of tortillas are fantastic, but my family was handed down a wheat flour tortilla tradition from my Mexican great grandmother Guadalupe Otila Macias, and since I was a wee child I’ve been truly mesmerized by this type.

Watching my grandmother mix and knead them by hand, roll them out with a flick or two of the wrist, and then bake them on top of a cast-iron griddle on the stove–the incredible smell–and then passing one steaming and blistered with flavor from hand to hand with nearly burnt fingertips, taking bites and smiling uncontrollably. These are some of the most powerful memories of my childhood. Why would I ever want to change a single detail in my original family recipe?

As I mentioned previously, wheat flour tortillas can be tricky because the gluten proteins in wheat (i.e., glutenin and gliadin) when hydrated, help to create a stretchy and springy dough that is notoriously hard to roll out. To produce a less tough and easier to roll tortilla, people traditionally added some amount of fat to the dough in the form of freshly rendered pork lard. The added lard reduces the overall gluten development, and the tortillas become more aromatic and the mouthfeel more tender and less chewy. And when everything is just right, the tortillas puff magically like perfect little pillows, making them even lighter in texture. But what about when everything isn’t just right?

tortillas freshly cooked
Freshly griddled wheat-flour tortillas made with freshly rendered pork lard, filtered water, and sea salt

The Baking Powder Bandage

The problem is that getting the ratio of ingredients just right can be very tricky. If it is even a bit off, or the griddle temperature is not optimal, or the tortilla maker is just not paying the right amount of attention, the tortillas can end up dense and unpleasant. The solution to this problem used by most is an addition of baking powder. It allows the tortilla maker a bit more flexibility in all of the important conditions. However, the texture of a baking-powder-risen tortilla is not quite the same as one without, and it has been written more than once by tortilla aficionados that the baking powder version is simply not as good.

The Vegetable Oil Blunder

Another problem is that as refined plant-based vegetable oils have become much cheaper, and good fatback from which to make lard has become less readily available in the marketplace, recipes have begun to call for either liquid oil or hydrogenated oil, also called shortening. These oil-based tortillas simply aren’t capable of tasting as good as those made from the roasted and rendered fat of flavorful hogs.

So, the modern homemade wheat-flour tortilla, which itself is scarce compared to the store-bought versions with little personality, is itself a shadow of its former glorious self. But if these changes to the modern tortilla have led to a poverty of quality, what is to be done about it? How can we possibly attempt to recreate a product formulation that most of us have never tasted?

I’ll explain how I approached this challenge in an effort to do just that. Stay tuned for más detalles in Part 3.

–Alan McClure

Filed Under: Food & Beverage Facts, Process Optimization Tagged With: chemistry, food, Mexican, product development, science, tortillas

Product Formulation Optimization #1

September 15, 2021 by Alan McClure

The Troublesome Yet Terrific Tortilla (Part 1)

From the standpoint of the uninitiated, a tortilla seems a simple beast. As a plain product on its own there are no fillings or inclusions, no added flavors, swirls of color, or fancy shapes. Even the plastic bags in which they’re sold ten at a time are nothing special. But the phrase “deceptively simple” does exist for a reason. And one could reasonably argue that it was coined as a product formulation expert was doing some deep thinking about the common, yet commonly unimpressive, tortilla.

So where should we start to understand the product formulation challenge better? It’s often the case that the very best examples of foods are traditional ones. And certainly where tortillas are concerned, traditional versions are far better than the most familiar brands at the local grocer. For those who have had incredible tortillas, the kind that are calling out to be eaten, simply, steaming hot from the Mexican comal, fingers burning, we know this in our gut. But if one wants this beautiful experience far away from a Mexican market or abuela, is it even possible?

What is a tortilla anyway?

First, let’s simplify the issue. Tortillas come in two main types: corn- and wheat-flour-based. Corn tortillas are traditionally made from alkali-treated heirloom corn, called “nixtamal,” a Nahuatl term borrowed from the Aztec. This process, often referred to as nixtamalization, uses a relatively dilute solution of culinary lime, aka calcium hydroxide, in water to catalyze hydrolysis and conversion of various compounds in the corn kernels’ hull. This process makes the corn easier to digest, more nutritious, less likely to contain harmful mycotoxins, and most people would claim, myself included, more delicious. In fact, the flavor is so good, that traditional corn tortillas require nothing more than ground nixtamal, water, and bit of salt, to create a fabulous flat food fit for an Aztec king. But, as previously mentioned…

Corn is not the only way…

In northern Mexico and Texas, which also used to be part of Mexico, where wheat flour was more readily available, tortillas made from this grain were more common. And because the proteins in wheat, when hydrated, help to create a stretchy and springy dough that is notoriously hard to roll out, people added some amount of fat to the dough in the form of freshly rendered pork lard. The lard reduced the overall gluten development, making the thin disks of dough easier to roll out, and moreover, made the tortillas more aromatic and the mouthfeel more tender than chewy. And when the proportions of flour:water:lard are just right, the tortillas puff magically, making them lighter and more tender in texture, and giving the surface of the tortilla a deliciously mottled appearance, due to light charring of the steam-puffed pockets on the surface, thereby creating even more flavor–Maillard reaction pathways y’all.

tortillas freshly cooked
Freshly griddled wheat-flour tortillas made with freshly rendered pork lard, filtered water, and sea salt

Now, I’m a sucker for both types of tortilla, and I’ve made countless batches of both, nixtamalizing my own corn, experimenting with many of the countless heirloom Mexican varieties, and for the wheat tortillas, rendering my own lard, getting the roasted, almost smoky pork flavor just right. But I have to admit that having grown up with wheat flour tortillas in my family, a cultural contribution of my Mexican maternal great-grandmother, Guadalupe Otila Macias, who emigrated to Texas as a young girl, I have spent considerably more time thinking about, making, and certainly eating wonderful wheat flour tortillas. And I can assure you that even with four ingredients, they are tricky to perfect, or more technically, to optimize the product formulation.

But I’ll tell you what; recently I did just that. Stay tuned for más detalles in Part 2.

–Alan McClure

Filed Under: Food & Beverage Facts, Process Optimization Tagged With: chemistry, food, Mexican, product development, science, tortillas

Microbes May Make Mouths Merry

August 1, 2021 by Alan McClure

Sometime back I came across an article at Science Daily that got me thinking about the impact of our little microbial friends on the flavor of our favorite foods and beverages. The authors of the study noted that certain normally tasteless compounds, when exposed to microbes that are naturally present in the mouth and/or throat, are transformed into aromatic flavor compounds, in some cases even giving off the characteristic odor of a particular food in the aftertaste.

Thinking about the variety of foods and beverages that I’ve tasted over my life, some with magnificent, long-lasting finishes, and others that seem to spiral so quickly to an unsatisfying demise, it makes me wonder to what extent the microbes in my mouth had any say in the matter. There are countless implications to all of this, including whether it is possible to optimize conversion by the microbes by altering the flavorless reactant concentration, but also potentially by altering environmental conditions in the mouth (e.g., pH, calcium or sodium ion concentration, amount of saliva, etc.).

That’s lots of food for thought, so to speak, and speaking of thought, who knows, maybe they’ll find out that there are microbes that change the way we think as well.

-Alan McClure

Filed Under: All posts, SCIENCE Tagged With: beverage, chemistry, chocolate, flavor, microbes, optimize

The Chemistry of Chocolate

August 1, 2021 by Alan McClure

Chocolate has perhaps the most complex flavor of any food in the world. With the running count now numbering at least 40,000 compounds found in cacao/cocoa beans, this means that even the simply fermented “cocoa bean comprises more detectable and resolvable analytes than any other processed food thus investigated (Milev et al, Food Research International, 2014).”  This is undoubtedly part of the reason that scientists struggle to tell us exactly which of the thousands of compounds give chocolate its magnificent, delectable and unmistakable flavor. It is perhaps most likely that this quintessential chocolate aroma is due to a combination of the many chemicals produced during roasting through various Maillard reaction pathways, but it may also potentially be due to an as yet undiscovered compound present at a very low concentration, yet still perceptible due to its very low odor threshold. And so it is at the start of the 21st century, as we find ourselves at the dawn of space tourism, regularly cloning plants and animals, and building supercomputers smaller than wristwatches, that we still can’t fully explain why chocolate is so gosh darn chocolaty.

However, even though there is so much we still don’t understand about chocolate, we do know that many people, if asked to choose between their favorite chocolate and any other beloved food, would not hesitate to choose what Carolus Linnaeus regarded as “food of the gods” (i.e., Theobroma cacao), and this despite the fact that cacao cotyledons just off the tree taste incredibly bitter and astringent, and not chocolaty in the least. How does such a transformation from detestable to exceptional occur?

It’s in the processing, including fermentation, drying, roasting, refining, and conching.  More specifically, it is our control over and optimization of the chemical-based flavor changes during chocolate processing that eventually reveal to us a flavor of beauty! And who am I to argue with anyone who believes that this achievement is equally as impressive as Jeff Bezos strapped into a flaming phallic vessel shooting for the stars.

-Alan McClure

Filed Under: All posts, SCIENCE Tagged With: cacao, chemistry, chocolate, cocoa beans, optimization, processing

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